PT8351 Fundamentals Of Polymer Science Lecture Notes
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PT8351 FUNDAMENTALS OF POLYMER Science
UNIT I BASIC CONCEPTS OF POLYMER
Basic concepts of macromolecules
– Monomers - Functionality - Classification and nomenclature of polymers -
Types of polymers. Step growth polymerization - Mechanism - Kinetics -
Bi-functional systems Poly functional
systems.
UNIT II POLYMERIZATION MECHANISM
Addition polymerization Mechanism
and kinetics of free radical – Cationic – Anionic Polymerisation - Initiator
systems - Chain length and degree of Polymerization – Control of molecular
weight - Chain transfer - Inhibition Coordination polymerization- Mechanism – Kinetics
- Ring opening polymerization-Atom transfer radical-polymerization. Reversible
Addition Fragmentation Termination (RAFT).
UNIT III COPOLYMERIZATION
MECHANISM
Copolymerization - Mechanism and
Kinetics of free radical - Ionic copolymerization -Determination of Monomer
reactivity ratios. Polymerization techniques - Bulk polymerization - Solution polymerization - Suspension
polymerization - Emulsion polymerization – Interfacial condensation.
UNIT IV POLYMER MOLECULARWEIGHT
Molecular weight- Molecular
weight averages - Molecular weight distribution - Unidispersity, polydispersity,
Degree of polymerization. Molecular weight determination - Basic concepts of
end group analysis, colligative properties, osmametry, light scattering, and
gel permeation chromatography - Viscosity of polymers solutions.
UNIT V REACTIONS OF POLYMERS
Chemical reactions of polymers –
Addition and substitution reactions - Hydrolysis – Acidolysis – inolysis – cross
linking reactions. Polymer degradation – Mechanical degradation – Oxidative degradation – Hydrolytic degradation – Photo
degradation.
TEXT BOOKS:
1. F.W. Billmeyer, “Textbook of
Polymer Science”, Wiley international publishers, 2008, 3rd Edition.
2. V.R. Gowariker,N.V.
Viswanathan, Jayadev Sreedhar, “Polymer Science” – New Age International (P)
Ltd, Publishers, 2015, 2nd edition.
3. George Odian, “Principles of
polymerisation”, Wiley international publishers, 2004, 4th Edition.
REFERENCES:
1. JM.G. Cowie, “Polymers:
Chemistry and Physics of Modern Materials”, Blackie, and London, 1991.
2. R.J. Young and P.Lovell,
“Introduction to Polymers”, 2nd Ed., Chapman & Hall, 1991.
3. Premamoy Ghosh, “Polymer
Science and Technology of Plastics and Rubbers”, Tata McGraw- Hill, New Delhi,
1990
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