ML8302 Thermodynamics And Kinetics Of Materials Lecture Notes Syllabus Book Previous 2 13 15 Marks Anna University Important Question Bank With Answers Regulation 2017 Study Materials Pdf Ppt

ML8302 Thermodynamics And Kinetics Of Materials Lecture Notes Syllabus Book Previous  2 13 15 Marks  Anna University Important Question Bank With Answers  Regulation 2017 Study Materials Pdf Ppt

ML8302 THERMODYNAMICS AND KINETICS OF MATERIALS

UNIT I FUNDAMENTAL CONCEPTS 

Definition of thermodynamic terms; concept of states, systems, equilibrium. Equation of states,

extensive and intensive properties, homogeneous and heterogeneous systems. Phase diagrams, Internal energy, heat capacity, enthalpy, isothermal, and adiabatic processes. 

UNIT II INTERNAL ENERGY AND ENTROPY

First law of Thermodynamics: Relation between Heat and work, Internal energy, Enthalpy. The  Second law of thermodynamics: Spontaneous process, Degree of measure of reversibility and

irreversibility, Maximum work, criteria of equilibrium. Combined statement of first and second laws on thermodynamics. Statistical interpretation of entropy: Concept of microstate, most probable

microstate, Thermal equilibrium, Boltzman equation

UNIT III AUXILARY FUNCTIONS AND THERMODYNAMIC POTENTIALS 

Auxiliary functions: Helmholtz, Gibbs free energy, Maxwell’s equation, Gibbs-Helmholtz equations.

Concept of Third law, temperature dependence of entropy, statistical interpretation of entropy, Deby  and Einstein concept of heat capacity, relation between Cp and Cv, Consequences of third law. Zeroth

law of thermodynamics and its applications. Thermodynamic potentials: Fugacity, Activity and Equilibrium constant. Clausius - Clayperon equation. Le Chatelier’s principle, Vant Hoff’s equation.

UNIT IV THERMODYNAMICS OF SOLUTIONS 

Solutions, partial molal quantities, ideal and non-ideal solutions, Henry’s law, Gibbs - Duhem

equation, regular solution, quasi-chemical approach to solution, statistical treatment. Change of

standard state. Phase relations and phase rule-its applications. Free energy composition diagrams for binary alloy systems, determination of liquidus, solidus and solvus lines. Effect of pressure on phase transformation and phase equilibria.

UNIT V THERMODYNAMICS OF REACTIONS 

Thermodynamics of electrochemical cells, solid electrolytes. Basic - Pourbaix diagrams.  Thermodynamics of Surfaces: Adsorption isotherms, Effect of surface energy on pressure and phase transformation temperature. Thermodynamics of Defects in solids: Point defects, vacancies and interstitials in solid metals.

TEXT BOOKS:

1. Boris.S.Bokstein, Mikhail I. Mendelev, David J. Srolovitz, "Thermodynamics and Kinetics in Materials science", Oxford University Press 2005.

2. David R Gaskell, “Introduction to the Thermodynamics of materials”, Taylor and Francis, Fifth edition, 2008.

REFERENCES:

1. Ahindra Ghosh, T"extbook of Materials and Metallurgical Thermodynamics", Prentice hall of  India, 2003.

2. DeHoff R T, "Thermodynamics in Materials Science", McGraw Hill, New York 1993.

3. David V Ragone, “Thermodynamics of Materials - Volume-1”, John Wiley & Sons, Inc. 1995.

4. Darken LS and Gurry R W ,”Physical Chemistry of Metals”, McGraw Hill, 1987.

5. J J Moore, “Chemical Metallurgy”, Butterworth-Heinemann Ltd, 1990.

6. Prasad, Krishna Kant, Ray, H. S. and Abraham, K. P., “Chemical and Metallurgical Thermodynamics”, New Age International, 2006

7. Peter Atkins, Julio de Paula, Physical Chemistry Volume 1: Thermodynamics and Kinetics,W. H. Freeman & Company, 2010

8. Swalin R A, “Thermodynamics of solids”, John Wiley Sons Inc, third edition, 1966.

9. Thomas Engel, Philip Reid, "Thermodynamics, Statistical Thermodynamics and Kinetics", Pearson

Education (LPE) 2007.

10. Upadhyaya, G. S. and Dube, R. K., “Problems in Metallurgical Thermodynamics and Kinetics”,

Pergamon Press, London, 1977.

ML8302 Thermodynamics And Kinetics Of Materials Lecture Notes Syllabus Book Previous  2 13 15 Marks  Anna University Important Question Bank With Answers  Regulation 2017 Study Materials Pdf Ppt